In the opening match of the Champions League group stage, Atletico Madrid played away against Liverpool. Llorente scored in the first half to give Atletico Madrid the lead. Across his Champions League career, Llorente has now scored 5 goals against Liverpool, accounting for half of his total 10 Champions League goals.

Following his goal in the first half against Liverpool, Llorente has scored 5 times in 5 matches against them in the Champions League, achieving a shot conversion rate of 83%.

Against all other opponents, Llorente has scored 5 goals in 54 matches, with a conversion rate of only 11%.

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