In the 4th round of La Liga, Barcelona played away against Valencia, where Fermín scored a goal in the first half. According to statistics, Fermín López became the first player to score 4 goals for Barcelona in the first 4 games of a La Liga season since Cesc Fàbregas in the 2011/12 season.

In this match against Valencia, Fermín also became the first player in the 2024/25 La Liga season to record both a goal and an assist within the first 25 minutes of a match.

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