On August 23 (CEST), Atlético Madrid officially announced their squad for their home La Liga match against Villarreal in the second round, with Álvarez included.

Atlético Madrid vs Villarreal Squad List:

Goalkeepers

J. Musso, Oblak, Salvi Esquivel

Defenders

J. M. Giménez, Hancko, Marc Pubill, Grimaldo, Le Normand, Jorge Domínguez, Daniel Martínez

Midfielders

Mendoza, Johnny, Koke, Lee, Barrios, M. Llorente, Morten Hjulmand, Jorge Castillo

Forwards

Baena, Lookman, Martín, Arnau Ortiz, Álvarez, and Giuliano

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