In the first round of the Champions League group stage, Liverpool vs. Atletico Madrid, Barcola was injured and left the field after 60 minutes.

This was Barcola's first start for Liverpool, having joined Liverpool in the summer transfer window for a transfer fee of 125 million euros.

Barcola played for 60 minutes and was substituted due to a calf injury. Barcola had 3 shots in the match, all of which were missed opportunities, with an expected goal value of 0.74, and he contributed 2 tackles on the defensive end.

Barcola's best chance of the match came in the 49th minute, when Liverpool launched a counterattack with a numerical advantage, and Barcola's one-on-one shot went wide under pressure from two defenders.

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